Nickel laterite: the HPAL–neutralise–precipitate family
The nickel-laterite flowsheet assembled from mechanisms taught earlier: high-pressure acid leaching (HPAL), staged neutralisation to reject iron and aluminium, and precipitation of a mixed hydroxide or sulfide nickel-cobalt product.
The idea
Nickel laterites — the oxide-ore half of the nickel world — are treated by high-pressure acid leaching and a precipitation back end. The flowsheet composes from mechanisms taught earlier, and this page assembles them, naming each contribution rather than re-teaching it.
The flowsheet in one line
Leach the laterite in sulfuric acid in an autoclave, neutralise the leach liquor in stages to throw out the iron and aluminium, and precipitate the nickel and cobalt as a mixed product: HPAL–neutralise–precipitate.
What each stage is doing
The leach is high-pressure acid leaching — the pressure-leaching mechanism of topic 4.6, the autoclave acting as the leach itself — dissolving the nickel and cobalt out of the laterite with sulfuric acid at high temperature and pressure. Neutralisation is precipitation by pH control, topic 6.2: lime or limestone raises the pH in stages so that iron and aluminium drop out as hydroxides first, ahead of the value, and the free acid is consumed. Precipitation of the product is topic 7.4: the nickel and cobalt are precipitated together as a mixed hydroxide (MHP) or mixed sulfide (MSP) intermediate, the form in which much laterite nickel is sold for downstream refining.
The defining numbers
The staged neutralisation lands on the lime slurry preparation calculator below — the reagent that consumes the free acid and lifts the pH. The autoclave leach itself reads on the sulfuric acid hub for the lixiviant property data; the nickel sulfate hub carries the property data for the dissolved value and the refined sulfate product. The autoclave heat balance is the pressure-leaching mechanism’s own subject (topic 4.6).
Where it differs from the others
Nickel laterite leads with an autoclave, like the copper concentrate (POX) variant, but its back end is precipitation rather than electrowinning: it makes an intermediate precipitate, not a finished metal. Cobalt rides with the nickel through the circuit and is separated downstream — often by the solvent extraction of topic 6.6 — which is why a nickel reader meets SX next.
Diagram
Go deeper
- Lime slurry preparation calculator →Calculator
Work the lime slurry strength for the staged neutralisation that rejects iron and aluminium and consumes free acid.
- Sulfuric acid hub →Substance hub
Read the sulfuric acid property data behind the high-pressure acid leach lixiviant.
- Nickel sulfate hub →Substance hub
Read the nickel sulfate property data behind the dissolved value and the refined product.
Sources
- •Crundwell, F.K., Moats, M.S., Ramachandran, V., Robinson, T.G. & Davenport, W.G., Extractive Metallurgy of Nickel, Cobalt and Platinum-Group Metals, 2011.
- •Free, M.L., Hydrometallurgy: Fundamentals and Applications, 2013.
- •Habashi, F., Textbook of Hydrometallurgy, 2nd ed., 1999.
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