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Hydrometallurgy fundamentals · Module 9 · 9.1

Gold: the leach–adsorb–elute–electrowin family

The gold flowsheet assembled from mechanisms taught earlier: cyanide tank leaching, carbon adsorption (CIL/CIP), elution and regeneration, and electrowinning — with the Merrill-Crowe zinc-cementation variant. The composing page for the path’s worked archetype.

TypeLearning topic — professional and student

The idea

Gold is the path’s worked archetype, and its flowsheet composes cleanly from mechanisms taught earlier in the program. This page assembles those mechanisms into the circuit a gold plant actually runs — it names each one and what it contributes, and points back to the topic that teaches it, rather than teaching it again. Read it as the door a gold reader enters through.

The flowsheet in one line

Leach the gold into solution with cyanide, load it from the slurry onto activated carbon, strip it back off into a small, rich eluate, and electrowin it to a metal product: leach–adsorb–elute–electrowin. Four mechanism stages, each its own topic, arranged into one circuit.

What each stage is doing

The leach is alkaline cyanide tank leaching — the residence-time-and-sizing mechanism of topic 4.3 — holding a stirred slurry long enough to dissolve the gold as its cyanide complex. Adsorption is topic 6.4: carbon is moved counter-current to the pulp through a train of tanks, loading the dissolved gold onto the solid. Where the ore is preg-robbing, the carbon goes into the leach tanks themselves — that is carbon-in-leach (CIL); where adsorption follows a finished leach, it is carbon-in-pulp (CIP). Elution and regeneration is topic 6.5: the loaded carbon is stripped in a hot caustic-cyanide eluate, and the stripped carbon is reactivated in a rotary regeneration kiln before it recirculates. Electrowinning is topic 7.1: the rich eluate is plated to a gold-bearing cathode product that goes to the refining boundary (topic 7.5).

The defining numbers

Four quantities size the circuit, and three of them land on a live calculator. The adsorption train is sized by slurry residence time across its tanks — the same online-volume-over-flow calculation as a leach train — on the CIL tank residence-time calculator below. The carbon inventory and advance rate that set the loading the carbon reaches land on the carbon advance & loading calculator. The regeneration-kiln residence time is the rotary-kiln sizing shared with calcination, on the kiln residence-time calculator. And the cyanide make-up strength of the leach solution lands on the cyanide solution preparation calculator.

The Merrill-Crowe variant

Where the leach solution is clarified rather than carried as slurry — a high-grade or silver-rich ore — the adsorption route is replaced by Merrill-Crowe cementation. The clarified solution (the clarification-and-polishing front end, topic 5.6) is de-aerated and contacted with zinc dust, and the gold cements onto the zinc by metal displacement: the cementation mechanism of topic 6.3. Adsorption and cementation are two different ways to take the gold out of solution onto a solid; which one a plant uses turns on whether it runs a slurry or a clarified liquor.

Where it differs from the others

Gold sits apart from the SX-EW commodities in how it concentrates the value: it adsorbs onto a solid (carbon or resin) or cements onto zinc, where copper and the base metals shuttle through an organic by solvent extraction. Its lixiviant is alkaline cyanide, not an acid sulfate; its recovery is electrowinning from a very dilute, very pure eluate. The barren solution and tailings still carry cyanide, which the closure module (topic 8.2) treats as process chemistry — destruction and neutralisation — and which is out of scope here.

Diagram

Gold: leach–adsorb–elute–electrowin (CIL/CIP)Gold: leach–adsorb–elute–electrowin (CIL/CIP)composes ↓Cyanide leach4.3Carbon adsorption (CIL/CIP)6.4Elution + regeneration6.5Electrowinning7.1Merrill-Crowe variant: clarify · de-aerate · zinc cementation (6.3)

Go deeper

Worked thread

Take the CIL tank residence-time calculator’s committed worked example for the adsorption stage of a gold circuit: a train of eight tanks, each 450 m³ working volume, fed slurry at 600 m³/h, online factor 100%, with a contextual carbon concentration of 15 kg/m³.

  1. 01Installed working volume: 8 × 450 = 3600 m³.
  2. 02Online volume at 100%: 3600 × 100 ÷ 100 = 3600 m³.
  3. 03Nominal residence time: 3600 ÷ 600 = 6.0 h.
  4. 04Order-of-magnitude carbon inventory: 3600 × 15 = 54,000 kg.
Result

The eight-tank train gives a 6.0 h slurry residence time and, at 15 kg/m³, holds an order-of-magnitude carbon inventory of 54,000 kg. The residence time is the hydraulic sizing the adsorption needs; the carbon inventory here is a contextual estimate, not a circuit-design figure.

Source

CIL Tank Residence Time Calculator committed worked example (8 tanks × 450 m³, 600 m³/h slurry, 100% online, 15 kg/m³ carbon).

Sources

  • Marsden, J. & House, I., The Chemistry of Gold Extraction, 2nd ed., 2006.
  • Adams, M.D. (ed.), Gold Ore Processing: Project Development and Operations, 2nd ed., 2016.
  • Stange, W., The process design of gold leaching and carbon-in-pulp circuits, Journal of the SAIMM, 99(1), 1999.
  • Habashi, F., Textbook of Hydrometallurgy, 2nd ed., 1999.

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