processconvert
Hydrometallurgy fundamentals · Module 5 · 5.5

Soluble loss: what poor washing costs

The dissolved metal that walks out in the liquor clinging to the washed solids — how it is quantified as a carried-liquor volume times a tenor, and why it is a direct revenue line. The committed CCD underflow sizes the volume the loss is charged against.

TypeLearning topic — professional and student

The idea

Every washing circuit loses some dissolved value, because the solids that leave it carry a film of liquor and that liquor holds metal in solution. Soluble loss is the name for the value that walks out of the plant dissolved in the underflow liquor of the last washing stage, and it is a direct line on the revenue statement — not a rounding error but, in a poorly washed circuit, a number large enough to decide whether the operation makes money. This topic is about quantifying it and seeing why it matters so directly.

The metal lost in the washed solids

When the final underflow leaves a CCD train it is a thickened slurry: solids plus the liquor clinging to them. The solids themselves may be barren residue, but the liquor is not — it is process solution, and it carries dissolved metal at whatever tenor the circuit runs. That liquor, and the value dissolved in it, leaves with the residue to the tailings. The loss is not the solids; it is the soluble value in the liquor the solids carry. Incomplete washing — too few stages, too low a wash ratio, channelling in a thickener bed — leaves that carried liquor more loaded than it needs to be, and the difference is value the plant dissolved and then discarded.

How it is quantified

Soluble loss is quantified as a volume times a tenor: the volume of liquor leaving with the final underflow, multiplied by the concentration of dissolved value in it. The carried-liquor volume comes straight from the underflow percent solids — the same figure the thickener and CCD calculators compute — and the tenor comes from the soluble balance across the wash train, which is where stage count and wash ratio do their work. Improving the wash drives the tenor of that carried liquor down; concentrating the underflow drives its volume down; both cut the loss. The worked thread below takes the committed CCD underflow liquor and shows the volume that any soluble loss is charged against.

Why it is a direct revenue line

What makes soluble loss sting is that it is recovered value discarded, not value never won. The leach already paid to dissolve that metal; the loss throws it away at the very last step, after every reagent and every kilowatt-hour of the upstream circuit has been spent on it. So a percentage point of soluble loss is a percentage point off saleable production at the full upstream cost, which is why washing efficiency is watched as closely as recovery and why the wash-ratio-versus-dilution trade of the previous topic is an economic decision rather than a housekeeping one. The CCD and dilution calculators below give the carried-liquor and make-up figures the loss is computed from; the tenor and the balance come from testwork on the circuit.

Diagram

Soluble loss: value recovered versus value lost in the carried liquordissolvedvalue inrecoveredto strong productlost in cakecarried liquor= V × tenorsoluble loss = carried-liquor volume × its soluble tenor

Now run it

  • Read the underflow liquor volume — the carried-liquor figure any soluble loss is charged against — from the dry solids rate and underflow wt% solids.

  • Solve C₁V₁ = C₂V₂ to relate a soluble tenor to the volume and strength of the solution it sits in when reasoning about loss and recovery.

Worked thread

Use the committed CCD wash-water example to size the liquor a soluble loss is charged against: 100 t/h dry solids at 55 wt% underflow, liquor 1000 kg/m³, target wash ratio 2.0, 160 m³/h wash water in place.

  1. 01Underflow slurry: 100 ÷ 0.55 = 181.82 t/h; liquor carried = 181.82 − 100 = 81.82 t/h = 81.82 m³/h at 1000 kg/m³.
  2. 02This 81.82 m³/h of underflow liquor is the volume any soluble value leaves dissolved in.
  3. 03Wash effect: at the 2.0 target the wash water is 163.64 m³/h; at the 160 m³/h in place the actual ratio is 1.96 — slightly less washing, so slightly more soluble value left in that 81.82 m³/h.
  4. 04Loss reads as volume × tenor: 81.82 m³/h × the soluble tenor of the carried liquor (g/L from the circuit’s soluble balance) = the dissolved value lost per hour.
Result

The final underflow carries 81.82 m³/h of liquor; soluble loss is that volume times the carried-liquor tenor, so cutting either the volume (a denser underflow) or the tenor (more washing) cuts the loss. The committed example sizes the volume; the tenor is a testwork input, not computed here.

Source

CCD Wash Water Calculator committed worked example (100 t/h, 55 wt% underflow, liquor 1000 kg/m³, wash ratio 2.0, 160 m³/h wash water); the soluble tenor comes from the circuit’s soluble balance.

Sources

  • Free, M.L., Hydrometallurgy: Fundamentals and Applications, 2013.
  • Wills, B.A. & Finch, J.A., Wills’ Mineral Processing Technology, 8th ed., 2016.
  • Marsden, J. & House, I., The Chemistry of Gold Extraction, 2nd ed., 2006.

Built and reviewed by a practising process engineer. About ProcessConvert →