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Hydrometallurgy fundamentals · Module 5 · 5.1

Thickening: settling, flocculation and underflow density

The settler you already know, with the hydromet layer added: flocculants build the settling rate, and underflow density is the variable you control the thickener on. From a target percent solids to the underflow slurry density and the liquor it carries.

TypeLearning topic — professional and student

The idea

Solid–liquid separation is home turf for anyone who has run a clarifier in water treatment, a settler in chemicals, or a decanter in oil and gas — the physics of letting solids fall out of a liquid under gravity is the same everywhere. What Module 5 adds is the hydrometallurgical layer: the separation is rarely the end of the job but the means of recovering dissolved value, the slurries are dense and abrasive, and the number a thickener is controlled on is its underflow density. This topic starts from the unit you already know and names what is different about it here.

Gravity thickening: the settler you already know

A thickener is a large, shallow, circular tank that does two jobs at once. Feed slurry enters through a central feedwell; the solids settle under gravity into a thickened bed that slow-moving rakes drag to a central underflow outlet, while clarified liquor overflows a peripheral launder at the rim. The clear overflow is recovered process liquor; the dense underflow is the thickened solids stream. It is the same sedimentation you have met as a clarifier, scaled and shaped for a duty where both products matter — the circuit wants the clear liquor back and the solids concentrated.

Flocculants build the settling rate

Fine mineral particles settle far too slowly on their own to be practical, so a thickener almost always runs with a flocculant — a long-chain polymer dosed into the feed that bridges fine particles into larger, faster-settling aggregates called flocs. The flocculant does not change what settles, only how fast: it raises the settling rate by orders of magnitude, which is what lets a thickener of a workable diameter carry the throughput. The dose and the polymer chemistry come from settling testwork on the actual slurry rather than a handbook, because the right flocculant depends on the mineralogy and the liquor — the same testwork-is-ground-truth rule the leaching modules drew.

Underflow density: the control variable

The number a thickener is operated and sized on is the underflow density — how concentrated the thickened solids stream is, quoted as percent solids by mass or as a slurry density. It is the control variable because it sets two things at once: how much liquor leaves with the solids (which, in a washing circuit, is soluble value carried away — the subject of this whole module), and whether the underflow is still pumpable. Take the underflow too dense and the rakes labour and the slurry stops flowing; run it too dilute and the circuit carries more liquor and recovers less water. The underflow-density calculator below converts a target percent solids into the slurry density and the component flows, on the same two-phase relation as the Module 2 slurry spine.

Underflow density and percent solids are the same statement in two units, tied by the house slurry-density relation — so the slurry-density calculator crosses between them, and the worked thread below runs the committed underflow example end to end.

Solids loading rate

The companion sizing number is the solids loading rate — the dry-solids mass a thickener handles per unit of its cross-sectional area per day, in t/m²/day. It is how the duty on an existing thickener of known diameter is checked against typical operating ranges, scaling with throughput against the tank area. The loading-rate calculator below computes it from the throughput and diameter as an operating check; sizing a new thickener from a settling flux is testwork-and-vendor territory, beyond what the arithmetic here represents.

Diagram

Gravity thickener: feedwell, rake, clear overflow, dense underflowfeed slurryfeedwellsettled bedrakeclear overflowrecovered liquordense underflowunderflow densitythe control variable

Now run it

  • Enter the dry solids rate, target underflow wt% solids, and the solids and liquid densities to get the underflow slurry density and the liquor it carries.

  • Enter the dry solids throughput and the thickener diameter to check the unit-area solids loading rate and the overflow rise rate against typical ranges.

  • Cross between underflow percent solids and slurry density on the house two-phase relation behind the underflow-density figure.

Worked thread

Take the thickener-underflow-density calculator’s committed worked example: 100 t/h dry solids leaving at 55 wt% underflow solids, solids density 2700 kg/m³, liquid density 1000 kg/m³. Find the underflow slurry density.

  1. 01Slurry mass: 100 ÷ (55 ÷ 100) = 181.82 t/h.
  2. 02Liquid mass: 181.82 − 100 = 81.82 t/h.
  3. 03Solids volume: 100 × 1000 ÷ 2700 = 37.04 m³/h.
  4. 04Liquid volume: 81.82 × 1000 ÷ 1000 = 81.82 m³/h.
  5. 05Slurry volume: 37.04 + 81.82 = 118.86 m³/h.
  6. 06Slurry density: 181.82 × 1000 ÷ 118.86 ≈ 1529 kg/m³.
Result

The 55 wt% underflow has a slurry density of about 1529 kg/m³ and carries 81.82 m³/h of liquor with the solids — that liquor figure being the soluble-loss exposure the rest of the module works on.

Source

Thickener Underflow Density Calculator committed worked example (100 t/h, 55 wt% solids, solids 2700 kg/m³, liquid 1000 kg/m³).

Sources

  • Wills, B.A. & Finch, J.A., Wills’ Mineral Processing Technology, 8th ed., 2016.
  • Perry, R.H. & Green, D.W. (eds.), Perry’s Chemical Engineers’ Handbook, 8th ed., 2008.
  • Concha, F. & Bürger, R., A century of research in sedimentation and thickening, KONA Powder and Particle Journal, 20, 2002.

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